I just tested the server with the command:
telnet mail.alphabizweb.com 25
..and the server appears to be responding properly there.
What could be happening is the web server, where ListMail is installed, cannot resolve and/or connect to the mail.alphabizweb.com domain...
Double-checking this, it appears the web site and mail server are the same computer/IP, so this shouldn't happen. Try a setting of "localhost" instead of "mail.alphabizweb.com".
Regards